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1,3,5‐Tris[(2‐hydroxy‐3,5‐diphenyl)phenyl]benzene and its Phenoxyl Radicals
Author(s) -
DeckertGaudig Tanja,
Hünig Siegfried,
Dormann Elmar,
Kelemen Marc Tibor
Publication year - 2001
Publication title -
european journal of organic chemistry
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.825
H-Index - 155
eISSN - 1099-0690
pISSN - 1434-193X
DOI - 10.1002/1099-0690(200104)2001:8<1563::aid-ejoc1563>3.0.co;2-s
Subject(s) - chemistry , benzene , radical , tris , electrochemistry , photochemistry , benzene derivatives , organic chemistry , medicinal chemistry , polymer chemistry , chemical synthesis , electrode , biochemistry , in vitro
The title compound 4 was synthesized, starting from 4‐hydroxybiphenyl ( 6 ), in a search for organic ferromagnets. Electrochemical and chemical oxidation of 4 resulted in a dark green, insoluble solid with the properties of a monoradical rather than the expected trisradical 4a .