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Preparation of Nitrogen‐Containing 15‐Membered Triolefinic Macrocycles: ( E,E,E )‐1,6,11‐Tris(arylsulfonyl)‐1,6,11‐triazacyclopentadeca‐3,8,13‐trienes
Author(s) -
Cerezo Silvia,
Cortès Jordi,
Galvan David,
Lago Elena,
Marchi Caroline,
Molins Elies,
MorenoMañas Marcial,
Pleixats Roser,
Torrejón Javier,
Vallribera Adelina
Publication year - 2001
Publication title -
european journal of organic chemistry
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.825
H-Index - 155
eISSN - 1099-0690
pISSN - 1434-193X
DOI - 10.1002/1099-0690(200101)2001:2<329::aid-ejoc329>3.0.co;2-n
Subject(s) - chemistry , tris , nitrogen , medicinal chemistry , polymer chemistry , stereochemistry , organic chemistry , biochemistry
Three routes to ( E,E,E )‐1,6,11‐tris(arylsulfonyl)‐1,6,11‐triazacyclopentadeca‐3,8,13‐trienes are described. Optimization of the preparation of key intermediates has opened the way to efficient synthesis of a broad variety of 15‐membered, nitrogen‐containing triolefinic macrocycles.