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Synthesis of Galactofuranosides by Regioselective Ring Opening of a 1,4‐Anhydrogalactopyranose Derivative: A Possible Chemical Model for an Unprecedented Enzymatic Reaction
Author(s) -
Kovensky José,
Sinaÿ Pierre
Publication year - 2000
Publication title -
european journal of organic chemistry
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.825
H-Index - 155
eISSN - 1099-0690
pISSN - 1434-193X
DOI - 10.1002/1099-0690(200011)2000:21<3523::aid-ejoc3523>3.0.co;2-c
Subject(s) - chemistry , regioselectivity , derivative (finance) , ring (chemistry) , enzyme , stereochemistry , organic chemistry , chemical synthesis , combinatorial chemistry , computational chemistry , catalysis , biochemistry , financial economics , economics , in vitro
The known 1,4‐anhydro‐2,3,6‐tri‐ O ‐benzyl‐β‐ D ‐galactopyranose ( 1 ) has been regioselectively ring‐opened using a variety of nucleophiles under acidic conditions to exclusively afford furanosides.