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Flash Vacuum Thermolysis Synthesis of New Reactive Compounds Containing a Silicon−Heteroatom Double Bond
Author(s) -
Levillain Jocelyne,
PfisterGuillouzo Geneviève,
Ripoll JeanLouis
Publication year - 2000
Publication title -
european journal of organic chemistry
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.825
H-Index - 155
eISSN - 1099-0690
pISSN - 1434-193X
DOI - 10.1002/1099-0690(200010)2000:19<3253::aid-ejoc3253>3.0.co;2-k
Subject(s) - chemistry , thermal decomposition , reactive intermediate , mass spectrometry , heteroatom , flash (photography) , double bond , monomer , silicon , photochemistry , combinatorial chemistry , organic chemistry , ring (chemistry) , art , polymer , chromatography , visual arts , catalysis
Flash vacuum thermolysis (FVT) afforded access to various unstable heterosilenes belonging to the silanimine (R 2 Si=NR′), phosphasilene (R 2 Si=PR′) and silanethione (R 2 Si=S) families. These extremely reactive monomeric compounds have been characterized in the gas phase by direct coupling of FVT with mass, millimetre wave and, particularly, photoelectron spectrometry.