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Synthesis of the Enantiomers of anti ‐2,6‐Dimethylheptane‐1,7‐diol Monotetrahydropyranyl Ether and Their Conversion into the Enantiomers of the Sex Pheromone Components of the Apple Leafminer, Lyonetia prunifoliella
Author(s) -
Nakamura Yoshihide,
Mori Kenji
Publication year - 2000
Publication title -
european journal of organic chemistry
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.825
H-Index - 155
eISSN - 1099-0690
pISSN - 1434-193X
DOI - 10.1002/1099-0690(200008)2000:15<2745::aid-ejoc2745>3.0.co;2-i
Subject(s) - enantiomer , chemistry , diol , sex pheromone , pheromone , ether , stereochemistry , organic chemistry , botany , biology
Both (2 R ,6 R )‐ and (2 S ,6 S )‐isomers of 2,6‐dimethylheptane‐1,7‐diol monotetrahydropyranyl ether ( 4 ) were synthesized, and converted into the enantiomers of anti ‐10,14‐dimethyl‐1‐octadecene ( 1 ), anti ‐5,9‐dimethyloctadecane ( 2 ) and anti ‐5,9‐dimethylheptadecane ( 3 ), the sex pheromone components of the apple leafminer ( Lyonetia prunifoliella ).