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Synthesis of (3 S ,7 S )‐ and (3 S ,7 S ,15 S )‐ Stereoisomers of 3,7‐Dimethyl‐2‐heptacosanone and 3,7,15‐Trimethyl‐2‐heptacosanone, the Ketones Identified from the Locust Schistocerca gregaria
Author(s) -
Nakamura Yoshihide,
Mori Kenji
Publication year - 2000
Publication title -
european journal of organic chemistry
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.825
H-Index - 155
eISSN - 1099-0690
pISSN - 1434-193X
DOI - 10.1002/1099-0690(200004)2000:7<1307::aid-ejoc1307>3.0.co;2-x
Subject(s) - schistocerca , chemistry , stereochemistry , organic chemistry , locust , botany , biology
Abstract The (3 S ,7 S ) and (3 S ,7 S ,15 S ) stereoisomers of 3,7‐dimethyl‐2‐heptacosanone ( 1 ) and 3,7,15‐trimethyl‐2‐heptacosanone ( 2 ), the ketones identified from the locust Schistocerca gregaria , were synthesized by employing (2 R ,6 S )‐7‐acetoxy‐2,6‐dimethyl‐1‐heptanol ( 4 ) as the starting material.