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Meltable Stannaborate Salts
Author(s) -
Ronig Benno,
Pantenburg Ingo,
Wesemann Lars
Publication year - 2002
Publication title -
european journal of inorganic chemistry
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.667
H-Index - 136
eISSN - 1099-0682
pISSN - 1434-1948
DOI - 10.1002/1099-0682(20022)2002:2<319::aid-ejic319>3.0.co;2-0
Subject(s) - chemistry , alkylation , alkyl , ion , melting point , inorganic chemistry , organic chemistry , medicinal chemistry , catalysis
In a one‐pot procedure, four imidazolium salts of alkylated stanna‐ closo ‐dodecaborate anions were synthesized. Alkyl substituents at the stannaborate anion and imidazolium cation were varied between ethyl and butyl, resulting in a range of melting points from 55 to 105 °C. The structures in the solids were determined in the case of [EMIM][Et−SnB 11 H 11 ] ( 1 ) and [EMIM][Bu−SnB 11 H 11 ] ( 2 ).