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A Novel Chiral Silver( I ) Complex from the Reaction of Thiazolidinethione with AgOAc
Author(s) -
Shi Min,
Jiang JianKang,
Zhao GuiLing
Publication year - 2002
Publication title -
european journal of inorganic chemistry
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.667
H-Index - 136
eISSN - 1099-0682
pISSN - 1434-1948
DOI - 10.1002/1099-0682(200212)2002:12<3264::aid-ejic3264>3.0.co;2-a
Subject(s) - chemistry , octahedron , dichloromethane , crystallography , cluster (spacecraft) , ligand (biochemistry) , crystal structure , stereochemistry , organic chemistry , biochemistry , receptor , solvent , computer science , programming language
A novel chiral silver( I ) complex was successfully synthesized from the reaction of chiral ( S )‐4‐isopropylthiazolidine‐2‐thione ligand ( 1 ) with AgOAc in dichloromethane in the presence of Et 3 N and DMAP at room temperature. Its unique crystal structure was unambiguously disclosed by X‐ray analysis. The six silver atoms and six ( S )‐4‐isopropylthiazolidine‐2‐thione ligands present in the complex are connected through the S and N atoms to form a cluster containing a silver octahedron with six faces of the octahedron capped by ligands. (© Wiley‐VCH Verlag GmbH, 69451 Weinheim, Germany, 2002)