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A New Synthetic Strategy for Magnetic Metal Bis(dithiolene) Based Conductors
Author(s) -
Mulder Martijn J. J.,
Haasnoot Jaap G.,
Stufkens Derk J.,
Tjeng Liu Hao,
Lin HongJi,
Chen ChienTe,
Reedijk Jan
Publication year - 2002
Publication title -
european journal of inorganic chemistry
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.667
H-Index - 136
eISSN - 1099-0682
pISSN - 1434-1948
DOI - 10.1002/1099-0682(200212)2002:12<3083::aid-ejic3083>3.0.co;2-o
Subject(s) - chemistry , paramagnetism , imine , raman spectroscopy , electron paramagnetic resonance , metal , magnetic susceptibility , crystallography , ion , electrical conductor , inorganic chemistry , catalysis , nuclear magnetic resonance , organic chemistry , condensed matter physics , materials science , physics , optics , composite material
The combination of the [Co III (Cl 2 ‐bpy) 3 ] 3+ complex with the [Ni(dmit) 2 ] − anion is a one‐step reaction, which results in the partially oxidised Ni(dmit) 2 ‐based material [Co II (Cl 2 ‐bpy) 3 ][Ni(dmit) 2 ] 5 with a paramagnetic Co II cation, as proven by Raman, EPR and XAS, exemplifying a, for M(dithiolene) 2 compounds new, synthetic strategy that may give access to a large variety of new [Co II (N,N‐imine) 3 ][M(dithiolene) 2 ] n ( n > 2, M = Ni, Pd) type magnetic conductors.