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1‐ and 2‐D Coordination Networks Based on Porphyrin and Copper: an Example of Supramolecular Isomerism
Author(s) -
Zimmer Bertrand,
Bulach Véronique,
Hosseini Mir Wais,
De Cian André,
Kyritsakas Nathalie
Publication year - 2002
Publication title -
european journal of inorganic chemistry
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.667
H-Index - 136
eISSN - 1099-0682
pISSN - 1434-1948
DOI - 10.1002/1099-0682(200212)2002:12<3079::aid-ejic3079>3.0.co;2-r
Subject(s) - chemistry , porphyrin , supramolecular chemistry , copper , coordination complex , combinatorial chemistry , crystallography , photochemistry , metal , organic chemistry , crystal structure
A high‐yield synthesis of atropoisomers of the meso ‐tetrakis( o ‐isonicotinoylamidophenyl)porphyrin was achieved. Depending on the crystallising solvent system, the α 2 β 2 atropoisomer leads to the formation of either 1‐D or 2‐D coordination networks in the presence of Cu(OAc) 2 .