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The Structure and Fluorescence Properties of Two Novel Mixed‐Ligand Supramolecular Frameworks with Different Structural Motifs
Author(s) -
Fu ZhiYong,
Wu XinTao,
Dai JingCao,
Hu ShengMin,
Du WenXin,
Zhang HanHui,
Sun RuiQing
Publication year - 2002
Publication title -
european journal of inorganic chemistry
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.667
H-Index - 136
eISSN - 1099-0682
pISSN - 1434-1948
DOI - 10.1002/1099-0682(200210)2002:10<2730::aid-ejic2730>3.0.co;2-g
Subject(s) - chemistry , terephthalic acid , supramolecular chemistry , photoluminescence , fluorescence , ligand (biochemistry) , metal organic framework , diamond , structural motif , crystallography , cobalt , polymer chemistry , crystal structure , inorganic chemistry , organic chemistry , polyester , biochemistry , physics , receptor , adsorption , quantum mechanics , optics
Abstract Two novel coordination polymers formed by cobalt nitrate and 1,2‐bis(4‐pyridyl)ethane with the homologous ligands 2‐aminoterephthalic acid and terephthalic acid, respectively, have been prepared. One displays a fivefold diamond‐type feature while the other exhibits a twofold interpenetrating structural motif. The thermal and photoluminescence properties associated with their structures have been characterized and studied. (© Wiley‐VCH Verlag GmbH, 69451 Weinheim, Germany, 2002)