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Chiral Supramolecular Assemblies Derived from the Insertion of a Segmental Ligand into a Copper‐Tyrosine Framework
Author(s) -
Weng Jiabao,
Hong Maochun,
Shi Qian,
Cao Rong,
Chan Albert S. C.
Publication year - 2002
Publication title -
european journal of inorganic chemistry
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.667
H-Index - 136
eISSN - 1099-0682
pISSN - 1434-1948
DOI - 10.1002/1099-0682(200210)2002:10<2553::aid-ejic2553>3.0.co;2-6
Subject(s) - chemistry , supramolecular chemistry , copper , tyrosine , ligand (biochemistry) , bipyridine , crystallography , stereochemistry , polymer chemistry , receptor , organic chemistry , crystal structure , biochemistry
The use of a predisposed 4,4‐bipyridine segmental ligand in copper‐tyrosine chiral complex self‐assembly processes allows the preparation of a new type of complex {[Cu 2 (tyrosine) 2 (4,4‐bipyridine)·2H 2 O]·2ClO 4 } n , which results in the fine tuning of network structure and stereo conformation. (© Wiley‐VCH Verlag GmbH, 69451 Weinheim, Germany, 2002)