Premium
Diels−Alder Synthesis of Rigid 60° Angular Bridging Ligands and X‐ray Crystal Structures of their Silver Nitrate Complexes
Author(s) -
Steel Peter J.,
Webb Nicholas C.
Publication year - 2002
Publication title -
european journal of inorganic chemistry
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.667
H-Index - 136
eISSN - 1099-0682
pISSN - 1434-1948
DOI - 10.1002/1099-0682(200209)2002:9<2257::aid-ejic2257>3.0.co;2-9
Subject(s) - chemistry , pyridine , crystal structure , silver nitrate , ligand (biochemistry) , bridging (networking) , nitrogen , polymer chemistry , silver salts , bridging ligand , crystallography , inorganic chemistry , organic chemistry , computer network , computer science , biochemistry , receptor
Using Diels−Alder chemistry, three bridging ligands ( 2 − 4 ) have been synthesised, each of which contains two pyridine nitrogen donors disposed at a 60° angle. X‐ray crystal structures are reported for ligand 4 and two coordination polymers formed by the reaction of 2 and 3 with silver nitrate. (© Wiley‐VCH Verlag GmbH, 69451 Weinheim, Germany, 2002)