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Synthesis, Structure, and Molecular Orbital Calculations of (Pyrazolato)vanadium(III) Complexes − Understanding η 2 ‐Pyrazolato Ligand Coordination on d 2 Metal Centers
Author(s) -
Gust Karl R.,
Knox John E.,
Heeg Mary Jane,
Schlegel H. Bernhard,
Winter Charles H.
Publication year - 2002
Publication title -
european journal of inorganic chemistry
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.667
H-Index - 136
eISSN - 1099-0682
pISSN - 1434-1948
DOI - 10.1002/1099-0682(200209)2002:9<2227::aid-ejic2227>3.0.co;2-f
Subject(s) - chemistry , vanadium , ligand (biochemistry) , metal , crystallography , molecular orbital , stereochemistry , inorganic chemistry , molecule , organic chemistry , receptor , biochemistry
The cover picture shows the structures of several vanadium( III ) complexes that contain η 2 ‐pyrazolato ligands, along with orbital interactions that stabilize the η 2 ‐pyrazolato ligand bonding mode. Details are discussed in the article by C. H. Winter et al. on p. 2327 ff.