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A Crystalline Phosphenium Salt Featuring the Electron‐Withdrawing 2,6‐Bis(trifluoromethyl)phenyl Group
Author(s) -
Dumitrescu Anca,
Gornitzka Heinz,
Schoeller Wolfgang W.,
Bourissou Didier,
Bertrand Guy
Publication year - 2002
Publication title -
european journal of inorganic chemistry
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.667
H-Index - 136
eISSN - 1099-0682
pISSN - 1434-1948
DOI - 10.1002/1099-0682(200208)2002:8<1953::aid-ejic1953>3.0.co;2-y
Subject(s) - chemistry , trifluoromethyl , salt (chemistry) , group (periodic table) , medicinal chemistry , organic chemistry , alkyl
The presence of a σ‐withdrawing group such as the 2,6‐bis(trifluoromethyl)phenyl substituent does not prevent the isolation of a highly electrophilic phosphenium salt. (© Wiley‐VCH Verlag GmbH, 69451 Weinheim, Germany, 2002)