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The [Re(CO) 6 ] + Cation as a Ligand‐Transfer Reagent with Ferrocene Derivatives
Author(s) -
Top Siden,
Masi Stéphane,
Jaouen Gérard
Publication year - 2002
Publication title -
european journal of inorganic chemistry
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.667
H-Index - 136
eISSN - 1099-0682
pISSN - 1434-1948
DOI - 10.1002/1099-0682(200207)2002:7<1848::aid-ejic1848>3.0.co;2-g
Subject(s) - chemistry , cyclopentadienyl complex , rhenium , reagent , ferrocene , ligand (biochemistry) , aqueous solution , aqueous medium , inorganic chemistry , polymer chemistry , medicinal chemistry , organic chemistry , catalysis , electrochemistry , biochemistry , receptor , electrode
The [Re(CO) 6 ] + cation is a stable compound, soluble in aqueous media. We show that it can be used as a reagent in the synthesis of tricarbonyl(cyclopentadienyl)rhenium complexes. [Re(CO) 6 ] + reacts with ferrocene derivatives, particularly acetylferrocene, in DMSO, DMF or a water/DMSO (1:1) mixture at 160 °C to give tricarbonyl(cyclopentadienyl)rhenium derivatives with high yields. (© Wiley‐VCH Verlag GmbH, 69451 Weinheim, Germany, 2002)