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Unusual Magnetic Behavior in the Layered Ferromagnet [Ni(C 6 H 14 N 2 ) 2 ] 3 [Fe(CN) 6 ] 2 ·2H 2 O
Author(s) -
Bellouard Frederic,
ClementeLeón Miguel,
Coronado Eugenio,
GalánMascarós José R.,
GómezGarcía Carlos J.,
Romero Francisco,
Dunbar Kim R.
Publication year - 2002
Publication title -
european journal of inorganic chemistry
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.667
H-Index - 136
eISSN - 1099-0682
pISSN - 1434-1948
DOI - 10.1002/1099-0682(200207)2002:7<1603::aid-ejic1603>3.0.co;2-t
Subject(s) - chemistry , ferromagnetism , coercivity , magnetization , condensed matter physics , magnetic susceptibility , crystallography , magnetic field , physics , quantum mechanics
The cyano‐bridged molecular complex [Ni(C 6 H 14 N 2 ) 2 ] 3 [Fe(CN) 6 ] 2 ·2H 2 O, with a rectangular 2D structure, displays long‐range ferromagnetic ordering at 14 K, and exhibits unusual magnetic properties for this type of material, as confirmed by the appearance of two different peaks in the AC magnetic susceptibility plot, and a high coercive field (2.3 kOe) and remnant magnetization (6.8 μ B ). (© Wiley‐VCH Verlag GmbH, 69451 Weinheim, Germany, 2002)