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cine and tele Nucleophilic Substitutions in (η 6 ‐Arene)tricarbonylchromium and Tricarbonyl(η 5 ‐cyclohexadienyl)manganese Complexes
Author(s) -
RoseMunch Françoise,
Rose Eric
Publication year - 2002
Publication title -
european journal of inorganic chemistry
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.667
H-Index - 136
eISSN - 1099-0682
pISSN - 1434-1948
DOI - 10.1002/1099-0682(200206)2002:6<1269::aid-ejic1269>3.0.co;2-9
Subject(s) - chemistry , nucleophile , manganese , medicinal chemistry , nucleophilic addition , stereochemistry , catalysis , organic chemistry
Addition of a nucleophile to an (η 6 ‐arene)tricarbonylchromium or a tricarbonyl(η 5 ‐cyclohexadienyl)manganese complex substituted with a leaving group X (X = F, Cl, OMe, OPh, NR 2 ) affords (after treatment with acid) new complexes with the same η 6 or η 5 hapticity. The overall reaction involves addition of the nucleophile ortho , meta , or para with respect to the leaving group and HX elimination. (© Wiley‐VCH Verlag GmbH, 69451 Weinheim, Germany, 2002)