Five‐Coordination and Adduct Formation in Co III −Corrinoids Dissecting Ligand Substitution into Its Component Steps | Zendy

Hamza Mohamed S. A. | Zendy; van Eldik Rudi | Zendy; Harper Pascal L. S. | Zendy; Pratt John M. | Zendy; Betterton Eric A. | Zendy

AI Assistant Blog Pricing

Home ZAIA Blog

Premium

Five‐Coordination and Adduct Formation in Co III −Corrinoids Dissecting Ligand Substitution into Its Component Steps

Author(s) -

Hamza Mohamed S. A.,

van Eldik Rudi,

Harper Pascal L. S.,

Pratt John M.,

Betterton Eric A.

Publication year - 2002

Publication title -

european journal of inorganic chemistry

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 0.667

H-Index - 136

eISSN - 1099-0682

pISSN - 1434-1948

DOI - 10.1002/1099-0682(200203)2002:3<580::aid-ejic580>3.0.co;2-z

Subject(s) - chemistry , adduct , ligand (biochemistry) , substitution (logic) , component (thermodynamics) , stereochemistry , molecule , coordination complex , base (topology) , organic chemistry , thermodynamics , biochemistry , physics , receptor , computer science , metal , programming language , mathematical analysis , mathematics

The equilibria between the five‐ and six‐coordinate species of alkylcobinamide and cobalamin (base‐off) have been studied using high‐pressure spectroscopic techniques. The addition of a water molecule to the five‐coordinate complex is accompanied by a volume decrease of 12 cm 3 ·mol −1 .

This content is not available in your region!

Continue researching here.

Having issues? You can contact us here

Accelerating Research