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Self‐Assembly of a Chiral Three Dimensional Architecture Composed of Two Different Silver(I) Helical Chains Connected by Bitopic Tris(pyrazolyl)methane Ligands
Author(s) -
Reger Daniel L.,
Semeniuc Radu F.,
Smith Mark D.
Publication year - 2002
Publication title -
european journal of inorganic chemistry
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.667
H-Index - 136
eISSN - 1099-0682
pISSN - 1434-1948
DOI - 10.1002/1099-0682(200203)2002:3<543::aid-ejic543>3.0.co;2-2
Subject(s) - chemistry , chirality (physics) , supramolecular chemistry , ligand (biochemistry) , methane , hydrogen bond , molecule , tris , crystallography , solvent , stereochemistry , self assembly , crystal structure , organic chemistry , receptor , biochemistry , physics , chiral symmetry breaking , quantum mechanics , nambu–jona lasinio model , quark
Abstract The coordination polymer { p ‐C 6 H 4 [CH 2 OCH 2 C(pz) 3 ] 2 Ag 2 (BF 4 ) 2 } n contains two opposite chirality metallohelicates, formed by a κ 2 , κ 1 bonding arrangement of each tris(pyrazolyl)methane unit, that are linked with the bitopic ligand into 2D sheets. The 3D supramolecular structure is formed by C−H ··· F weak hydrogen bonds that also order the solvent molecules.