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New Types of Complexes Based on Re 4 Chalcocyanide Clusters − Syntheses and Crystal Structures of [Ni(NH 3 ) 5 ] 2 [Re 4 Te 4 (CN) 12 ]·3.4H 2 O and [Cd(NH 3 ) 5 ][Cd(NH 3 ) 3 ][Re 4 Te 4 (CN) 12 ]·4H 2 O
Author(s) -
Mironov Yuri V.,
Oeckler Oliver,
Simon Arndt,
Fedorov Vladimir E.
Publication year - 2001
Publication title -
european journal of inorganic chemistry
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.667
H-Index - 136
eISSN - 1099-0682
pISSN - 1434-1948
DOI - 10.1002/1099-0682(200111)2001:11<2751::aid-ejic2751>3.0.co;2-8
Subject(s) - chemistry , triclinic crystal system , monoclinic crystal system , rhenium , crystallography , crystal structure , cluster (spacecraft) , aqueous solution , polyoxometalate , stereochemistry , nickel , inorganic chemistry , organic chemistry , computer science , programming language , catalysis
Two new tetrahedral rhenium chalcocyanidecluster compounds[Ni(NH 3 ) 5 ] 2 [Re 4 Te 4 (CN) 12 ]·3.4H 2 O( 1 ) and[Cd(NH 3 ) 5 ][Cd(NH 3 ) 3 ][Re 4 Te 4 (CN) 12 ]·4H 2 O( 2 ), exhibiting molecular ( 1 ) and chain‐like polymericstructures ( 2 ), have been synthesized by treatment of thesalt‐like cluster compoundK 4 Re 4 Te 4 (CN) 12 ·5H 2 Owith solutions of nickel acetate and cadmium sulfate, respectively, inaqueous ammonia. Both compounds have been characterized bysingle‐crystal X‐ray diffraction analysis. Compound 1 crystallizes in the monoclinic space group P 2 1 / c [ a = 19.572(3), b =14.849(2), c = 23.576(3) Å, β = 145.97(1)°, Z = 4, V = 3834.4(9) Å 3 ], whilecompound 2 crystallizes in the triclinic space group P $\bar 1$ [ a = 12.726(2), b = 13.408(2), c = 13.918(2) Å, α = 111.31(2), β = 116.77(2), γ = 90.17(2)°, Z = 2, V = 1935.3(5) Å 3 ].