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Rational Design of Open‐Framework Coordination Solids − Synthesis and Structure of [Co 5 (OH) 2 {1,2,4,5‐(O 2 C) 4 C 6 H 2 } 2 (H 2 O) 4 ]· x H 2 O
Author(s) -
Gutschke Siegfried O. H.,
Price Daniel J.,
Powell Annie K.,
Wood Paul T.
Publication year - 2001
Publication title -
european journal of inorganic chemistry
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.667
H-Index - 136
eISSN - 1099-0682
pISSN - 1434-1948
DOI - 10.1002/1099-0682(200111)2001:11<2739::aid-ejic2739>3.0.co;2-1
Subject(s) - chemistry , carboxylate , cobalt , hydrothermal synthesis , rational design , coordination complex , hydrothermal circulation , porosity , metal , ion , metal organic framework , inorganic chemistry , chemical engineering , stereochemistry , nanotechnology , organic chemistry , adsorption , materials science , engineering
A strategy for preparing open‐framework coordination solids by hydrothermal synthesis has been developed and tested by the synthesis of a new porous cobalt carboxylate which can be dehydrated by heating to give a material with coordinatively unsaturated metal ions.