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Versatile Behavior of β‐Heterosubstituted Zirconaindene Complexes: M−Cl Bond Activation (M = Si, P, Au Fragments)
Author(s) -
Owsianik Krzysztof,
Zablocka Maria,
Igau Alain,
Majoral JeanPierre,
Skowronska Aleksandra
Publication year - 2001
Publication title -
european journal of inorganic chemistry
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.667
H-Index - 136
eISSN - 1099-0682
pISSN - 1434-1948
DOI - 10.1002/1099-0682(200107)2001:7<1693::aid-ejic1693>3.0.co;2-f
Subject(s) - chemistry , crystallography , metal , electron deficiency , stereochemistry , organic chemistry
A new way of M−Cl bond activation (M = Si, P, Au fragments) is reported. It consists on the 1,2‐addition of M−Cl containing species on the Zr−N bond of azazirconaindene complexes. Unprecedented imino gold complexes incorporating two electron‐deficient metallic centers (Au, Zr) have been prepared.