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A Bis(carboxamido‐ N )diisocyanidobis(sulfenato‐ S )cobalt(III) Complex, Model for the Post‐Translational Oxygenation of Nitrile Hydratase Thiolato Ligands
Author(s) -
Heinrich Laurent,
Li Yun,
Vaissermann Jacqueline,
Chottard JeanClaude
Publication year - 2001
Publication title -
european journal of inorganic chemistry
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.667
H-Index - 136
eISSN - 1099-0682
pISSN - 1434-1948
DOI - 10.1002/1099-0682(200106)2001:6<1407::aid-ejic1407>3.0.co;2-p
Subject(s) - chemistry , nitrile hydratase , cobalt , isocyanide , nitrile , ligand (biochemistry) , medicinal chemistry , stereochemistry , combinatorial chemistry , inorganic chemistry , organic chemistry , biochemistry , receptor
A square‐planar cobalt(III) complex with an N 2 S 2 bis(carboxamido‐ N )dithiolato tetradentate ligand was oxygenated by H 2 O 2 ·urea, after axial coordination of tert ‐butyl isocyanide, to the first bis(carboxamido‐ N )bis(sulfenato‐ S )cobalt(III) complex.