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Metallic Palladium in the Heck Reaction: Active Catalyst or Convenient Precursor?
Author(s) -
Biffis Andrea,
Zecca Marco,
Basato Marino
Publication year - 2001
Publication title -
european journal of inorganic chemistry
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.667
H-Index - 136
eISSN - 1099-0682
pISSN - 1434-1948
DOI - 10.1002/1099-0682(200105)2001:5<1131::aid-ejic1131>3.0.co;2-3
Subject(s) - palladium , chemistry , catalysis , heck reaction , metal , polymer chemistry , organic chemistry , combinatorial chemistry , inorganic chemistry
Novel experimental evidence is presented pointing out that “heterogeneous” palladium metal catalysts employed in Heck‐type reactions mainly act as sources of soluble palladium(II) complexes, which are the true catalytically active species.