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Supramolecular Assembling of Dizinc Macrocyclic Complexes with Thymine and Uracil — The Role of Intra‐ and Intermolecular Hydrogen Bonding
Author(s) -
Bazzicalupi Carla,
Bencini Andrea,
Berni Emanuela,
Bianchi Antonio,
Ciattini Samuele,
Giorgi Claudia,
Paoletti Piero,
Valtancoli Barbara
Publication year - 2001
Publication title -
european journal of inorganic chemistry
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.667
H-Index - 136
eISSN - 1099-0682
pISSN - 1434-1948
DOI - 10.1002/1099-0682(200103)2001:3<629::aid-ejic629>3.0.co;2-n
Subject(s) - chemistry , supramolecular chemistry , intermolecular force , thymine , uracil , hydrogen bond , supramolecular assembly , coordination complex , crystallography , stereochemistry , crystal structure , molecule , organic chemistry , dna , metal , biochemistry
A binuclear Zn II complex with an oxa‐aza macrocyclic ligand can bind two deprotonated thymine or uracil moieties, giving versatile building blocks for the assembly of supramolecolar structures, by hydrogen bond pairing of the nucleobases.