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Fe 9 O 3 (OC 2 H 5 ) 21 ·C 2 H 5 OH − A New Structure Type of an Uncharged Iron(III) Oxide−Alkoxide Cluster
Author(s) -
Veith Michael,
Grätz Frank,
Huch Volker
Publication year - 2001
Publication title -
european journal of inorganic chemistry
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.667
H-Index - 136
eISSN - 1099-0682
pISSN - 1434-1948
DOI - 10.1002/1099-0682(200102)2001:2<367::aid-ejic367>3.0.co;2-v
Subject(s) - chemistry , alkoxide , cluster (spacecraft) , sodium ethoxide , inorganic chemistry , oxide , paramagnetism , magnetic moment , molecule , solid state , crystallography , organic chemistry , catalysis , computer science , programming language , physics , quantum mechanics , ethanol , condensed matter physics
A new nona iron(III) oxide‐alkoxide cluster has been prepared by the treatment of FeCl 3 with three equivalents of sodium ethoxide. The molecule is the first example of a neutral iron(III) alkoxide cluster based on OEt ligands and shows a paramagnetic moment of 13.4(1) μ B at 293 K in the solid state.