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Investigation of the Structure of New Gallium Phosphonate Based Hybrid Materials by 31 P, 71 Ga, and 1 H Solid‐State NMR
Author(s) -
BujoliDoeuff Martine,
Evain Michel,
Fayon Franck,
Alonso Bruno,
Massiot Dominique,
Bujoli Bruno
Publication year - 2000
Publication title -
european journal of inorganic chemistry
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.667
H-Index - 136
eISSN - 1099-0682
pISSN - 1434-1948
DOI - 10.1002/1099-0682(200012)2000:12<2497::aid-ejic2497>3.0.co;2-l
Subject(s) - gallium , chemistry , phosphonate , solid state , solid state nuclear magnetic resonance , nuclear magnetic resonance spectroscopy , trigonal crystal system , crystallography , crystal structure , stereochemistry , organic chemistry , nuclear magnetic resonance , physics
Modern high‐resolution solid‐state NMR is a powerful tool for probing the structure of phosphonate‐based hybrid materials, in the organic as well as in the inorganic region. This is illustrated in the case of a series of new gallium phosphonates [Ga(OH)(O 3 PCH 3 ) · x H 2 O [ x = 1 ( 1 ); x = 0 ( 1′ )] and Ga(OH)(O 3 PCH 2 C 6 H 5 ) ( 2 )], that were characterized by X‐ray diffraction and FTIR, and then studied using 71 Ga, 31 P, and 1 H NMR.