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A Three‐Dimensional, Cyano‐Bridged Cluster−Metal Coordination Compound with Large Cavities
Author(s) -
Fedin Vladimir P.,
Virovets Alexander V.,
Kalinina Irina V.,
Ikorskii Vladimir N.,
Elsegood Mark R. J.,
Clegg William
Publication year - 2000
Publication title -
european journal of inorganic chemistry
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.667
H-Index - 136
eISSN - 1099-0682
pISSN - 1434-1948
DOI - 10.1002/1099-0682(200011)2000:11<2341::aid-ejic2341>3.0.co;2-1
Subject(s) - chemistry , cluster (spacecraft) , crystallography , aqueous solution , diffusion , metal , porosity , organic chemistry , computer science , programming language , physics , thermodynamics
By very slow diffusion of aqueous solutions of CoCl 2 ·6H 2 O and K 6 [W 4 Te 4 (CN) 12 ]·5H 2 O through silica gel, single crystals of [Co(H 2 O) 4 ] 3 [W 4 Te 4 (CN) 12 ]·15.38H 2 O were obtained. A complete X‐ray structure determination reveals an extremely porous, three‐dimensional neutral cluster‐expanded framework structure with large water‐filled cuboidal cavities.