Premium
Borane‐stabilized Boranediyls (Borylenes): Neutral nido ‐1‐Borane‐2,3,4,5,6‐pentamethyl‐2,3,4,5,6‐pentacarbahexaboranes(6)
Author(s) -
Greiwe Peter,
Bethäuser Alexandra,
Pritzkow Hans,
Kühler Thorsten,
Jutzi Peter,
Siebert Walter
Publication year - 2000
Publication title -
european journal of inorganic chemistry
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.667
H-Index - 136
eISSN - 1099-0682
pISSN - 1434-1948
DOI - 10.1002/1099-0682(200009)2000:9<1927::aid-ejic1927>3.0.co;2-k
Subject(s) - chemistry , borane , adduct , lewis acids and bases , medicinal chemistry , stereochemistry , crystallography , organic chemistry , catalysis
The reaction of (C 5 Me 5 ) 2 Si or (C 5 Me 5 )SiMe 3 with B 2 Cl 4 leads to the adducts (C 5 Me 5 )B→BCl 2 SiCl 3 ( 5a ) or (C 5 Me 5 )B→BCl 3 ( 5b ), in which the Lewis acids stabilize the boranediyl fragments. Spectroscopic data and X‐ray structure analyses confirm the adducts.