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Evaluation of the oxidative stability of multiextruded polypropylene as assessed by physicomechanical testing and simultaneous differential scanning calorimetry–chemiluminescence
Author(s) -
Fearon Peter K.,
Marshall Niall,
Billingham Norman C.,
Bigger Stephen W.
Publication year - 2000
Publication title -
journal of applied polymer science
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.575
H-Index - 166
eISSN - 1097-4628
pISSN - 0021-8995
DOI - 10.1002/1097-4628(20010124)79:4<733::aid-app180>3.0.co;2-i
Subject(s) - differential scanning calorimetry , polypropylene , materials science , extrusion , calorimetry , melt flow index , nuclear chemistry , polymer chemistry , chemistry , composite material , copolymer , polymer , physics , thermodynamics
Common physicomechanical tests comprising impact strength, the melt flow index (MFI), and the yellowness index (YI) were used to study the thermooxidative stability of polypropylene (PP) following multipass extrusion. Differential scanning calorimetry (DSC) coupled with chemiluminescence (CL) monitoring was also used to assess the stability. Three PP formulations were studied: (i) PP‐1 containing 0.050% w/w of the phenolic antioxidant Irganox 1010 ™ , (ii) PP‐2 containing 0.028% w/w Irganox 1010, 0.056% w/w of the phosphite costabilizer Irgafos 168 ™ and 0.014% w/w of the lactone processing stabilizer HP 136 ™ , and (iii) PP‐3 containing 0.050% w/w Irganox 1010 and 0.100% w/w of the phosphite Ultranox 641 ™ . All formulations contained 0.045% w/w of the hydrotalcite acid scavenger DHT‐4A ™ . The results suggest that physicomechanical tests cannot reliably detect the small difference in the stability between PP‐2 and PP‐3 but can detect the larger difference between these and the less stable PP‐1. The oxidative induction time (OIT) determined by CL monitoring (i.e., CL– OIT) is consistent with the OIT determined by DSC but has better reliability. The CL–OIT data suggest that PP‐3 has superior oxidative stability to PP‐2 in the early stages of multipass extrusion. However, PP‐2 exhibits a better resistance to yellowing. A correlation between the CL–OIT data and each of the MFI and YI data was found. © 2000 John Wiley & Sons, Inc. J Appl Polym Sci 79: 733–741, 2001