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Curing of epoxy resin contaminated with water
Author(s) -
Chen Jingyuan,
Nakamura Takahiro,
Aoki Koichi,
Aoki Yuki,
Utsunomiya Toru
Publication year - 2000
Publication title -
journal of applied polymer science
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.575
H-Index - 166
eISSN - 1097-4628
pISSN - 0021-8995
DOI - 10.1002/1097-4628(20010110)79:2<214::aid-app30>3.0.co;2-s
Subject(s) - epoxy , materials science , curing (chemistry) , composite material , bisphenol a , diglycidyl ether , ultimate tensile strength , adhesive , flexural strength , absorption of water , synthetic resin , izod impact strength test , layer (electronics)
Epoxy resins used for reinforcement of bridges and buildings are explored in the light of both curing rates and mechanical properties when resins are contaminated with water in outdoor construction. The developed resin is composed of a conventional resin of bisphenol A diglycidyl ether and a hardener with a polyoxipropyldiamine base. Curing rates were obtained by time variation of the near infrared absorbance of amine groups in the hardener at various water contents. They obeyed the second‐order reaction law with respect to the hardener, of which the activation energy was 70 kJ mol −1 . Water increased the reaction rate. Mechanical properties such as ultimate tensile strength, adhesive shear stress, and flexural strength were measured at various water contents for the developed epoxy resin and the commercially available low‐temperature epoxy resin. The developed cured resin shows not only higher mechanical strengths but also much less deterioration by water than the conventional cured resin. © 2000 John Wiley & Sons, Inc. J Appl Polym Sci 79: 214–220, 2001