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Complexes of 1‐vinylazoles with transition metals in radical polymerization
Author(s) -
Danilovtseva E. N.,
Annenkov V. V.,
Skushnikova A. I.,
Svyatkina L. I.
Publication year - 2000
Publication title -
journal of applied polymer science
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.575
H-Index - 166
eISSN - 1097-4628
pISSN - 0021-8995
DOI - 10.1002/1097-4628(20001003)78:1<101::aid-app130>3.0.co;2-v
Subject(s) - polymerization , polymer chemistry , radical polymerization , polymer , chemistry , ionic polymerization , living free radical polymerization , transition metal , materials science , catalysis , organic chemistry
Radical polymerization of the complexes of 1‐vinylimidazole, 1‐vinylbenzimidazole, and 1‐vinylbenztriazole with MnCl 2 , NiCl 2 , and ZnCl 2 was investigated. It was found that the polymerization is accompanied by spontaneous polymerization in the case of MnCl 2 and ZnCl 2 , inhibition by coordination of macroradicals with Ni 2+ ions, and a gel effect by crosslinking of the formed polymer during the complexing with Zn 2+ . © 2000 John Wiley & Sons, Inc. J Appl Polym Sci 78: 101–108, 2000