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Evaluation of the film and adhesive properties of some block copolymer polyhydroxypolyamides from esterified aldaric acids and diamines
Author(s) -
Morton David W.,
Kiely Donald E.
Publication year - 2000
Publication title -
journal of applied polymer science
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.575
H-Index - 166
eISSN - 1097-4628
pISSN - 0021-8995
DOI - 10.1002/1097-4628(20000929)77:14<3085::aid-app90>3.0.co;2-7
Subject(s) - diamine , copolymer , monomer , polymer chemistry , condensation polymer , polymer , solubility , adhesive , polymerization , materials science , chemistry , condensation , organic chemistry , physics , layer (electronics) , thermodynamics
A number of structurally different block copolymer polyhydroxypolyamides (PHPAs), produced by condensation polymerization of activated aldarates with 1 o diamines, were evaluated for their water and methanol solubility and film‐forming and adhesive properties. The polymers are composed of a single aldaric acid and a single diamine unit, a single aldaric acid and two diamine units, two aldaric acids and a single diamine unit, or two aldaric acids and two diamine units. The aldaryl monomer units in the polymers were derived from D ‐glucaric, xylaric, and galactaric (mucic) acids. A number of alkylenediamines and heteroatom (oxygen and nitrogen)‐containing diamines were employed as comonomers. © 2000 John Wiley & Sons, Inc. J Appl Polym Sci 77: 3085–3092, 2000