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Dynamical Lie algebraic treatment for the A+BC scattering
Author(s) -
Yang Benhui,
Yin Hongming,
Han Keli,
Ding Shiliang
Publication year - 2000
Publication title -
international journal of quantum chemistry
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.484
H-Index - 105
eISSN - 1097-461X
pISSN - 0020-7608
DOI - 10.1002/1097-461x(2001)81:3<214::aid-qua4>3.0.co;2-f
Subject(s) - anharmonicity , algebraic number , quantum , scattering , physics , motion (physics) , quantum mechanics , lie algebra , collision , chemistry , mathematical physics , atomic physics , classical mechanics , mathematics , mathematical analysis , computer security , computer science
We report the study of translational‐vibrational energy transfer in the A+BC scattering using the dynamical Lie algebraic approach combined with the intermediate picture. The rotational sudden approximation is applied to treat the rotational motion of the BC molecule, which is regarded as an anharmonic oscillator. The calculated results show that the transition probabilities increase with increasing rotational quantum number. Comparison with those obtained in the collinear collision of system A+BC manifests that the transition probabilities here increase indeed. © 2001 John Wiley & Sons, Inc. Int J Quant Chem 81: 214–221, 2001