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Nonlinear coupling model for reactions in dense media
Author(s) -
Christov S. G.
Publication year - 2000
Publication title -
international journal of quantum chemistry
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.484
H-Index - 105
eISSN - 1097-461X
pISSN - 0020-7608
DOI - 10.1002/1097-461x(2001)81:1<1::aid-qua2>3.0.co;2-6
Subject(s) - transition state theory , nonlinear system , coupling (piping) , statistical physics , physics , thermodynamics , materials science , quantum mechanics , reaction rate constant , kinetics , metallurgy
A reaction rate theory for dense‐phase reactions, based on the assumption of nonlinear coupling between reactant and medium, is proposed. The relations between the exact dynamic theory, the stochastic rate theory, and the transition state theory is discussed. © 2001 John Wiley & Sons, Inc. Int J Quant Chem 81: 1–3, 2001