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Atom connectivity and spectral assignments from the 29 Si– 29 Si INADEQUATE experiment on a nanometer scale dendritic polysilane
Author(s) -
Lambert Joseph B.,
Wu Hongwei
Publication year - 2000
Publication title -
magnetic resonance in chemistry
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.483
H-Index - 72
eISSN - 1097-458X
pISSN - 0749-1581
DOI - 10.1002/1097-458x(200005)38:5<388::aid-mrc653>3.0.co;2-s
Subject(s) - chemistry , polysilane , trimethylsilyl , nanometre , scale (ratio) , molecule , atom (system on chip) , stereochemistry , nanotechnology , photochemistry , chemical engineering , medicinal chemistry , organic chemistry , quantum mechanics , physics , polymer , computer science , engineering , embedded system , materials science
The 29 Si– 29 Si 2D INADEQUATE spectrum was recorded for the dendritic polysilane tris[2,2,5,5‐tetrakis(trimethylsilyl)hexasilyl]methylsilane. This spectrum provides not only a complete assignment of all 29 Si resonances but also the Si–Si connectivity for the entire molecule. Copyright © 2000 John Wiley & Sons, Ltd.