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Kerr‐gated picosecond time‐resolved resonance Raman spectroscopic probing of the excited states in Λ‐[Ru(bipy) 2 dppz](BF 4 ) 2 (bipy = 2,2′‐bipyridyl, dppz = dipyrido[3,2‐ a :2′,3′‐ c ]phenazine)
Author(s) -
Benniston Andrew C.,
Matousek Pavel,
Parker Anthony W.
Publication year - 2000
Publication title -
journal of raman spectroscopy
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.748
H-Index - 110
eISSN - 1097-4555
pISSN - 0377-0486
DOI - 10.1002/1097-4555(200006)31:6<503::aid-jrs565>3.0.co;2-l
Subject(s) - phenazine , picosecond , raman spectroscopy , excited state , diimine , ruthenium , photochemistry , resonance (particle physics) , chemistry , resonance raman spectroscopy , acetonitrile , laser , optics , atomic physics , organic chemistry , physics , catalysis
Kerr‐gated picosecond time‐resolved resonance Raman spectra of an enantiomerically pure ruthenium(II) diimine intercalator complex in water and acetonitrile are reported, affording the first direct temporally resolved evidence that its excited state is structurally different in the two solvents. Copyright © 2000 John Wiley & Sons, Ltd.