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Influence of temperature on the volatilization of triallate and terbutryn from two soils
Author(s) -
Tabernero María T,
ÁlvarezBenedí Javier,
Atienza Julián,
Herguedas Andrés
Publication year - 2000
Publication title -
pest management science
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 1.296
H-Index - 125
eISSN - 1526-4998
pISSN - 1526-498X
DOI - 10.1002/(sici)1526-4998(200002)56:2<175::aid-ps111>3.0.co;2-e
Subject(s) - volatilisation , loam , soil water , sorption , environmental chemistry , chemistry , pesticide , environmental science , soil science , agronomy , adsorption , biology , organic chemistry
The rate of volatilization of the formulated herbicides triallate and terbutryn was studied in a volatilization chamber under controlled laboratory conditions using two soils with sand and loam textures, respectively. The influence of the most relevant experimental variables was investigated by measuring the amount of volatilized herbicides after their incorporation to the soils. The effect of soil temperature was studied in the range from 5 °C to 25 °C. Initial soil water content was fixed at field capacity depending on the physical characteristics of each soil. The volatilized herbicide was trapped in C18 cartridges during different time intervals and analyzed by HPLC. The volatilization losses for triallate ranged from 7 to 58%, whereas the losses for terbutryn ranged from 1 to 6%. Sorption and volatilization resulted in two coupled effects of major importance in these experiments: the sorption process was favoured as temperature decreased, whereas volatilization increased as temperature increased. © 2000 Society of Chemical Industry