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Hydrosilylation Reactions in Single and Two Phases
Author(s) -
Behr A.,
Toslu N.
Publication year - 2000
Publication title -
chemical engineering and technology
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.403
H-Index - 81
eISSN - 1521-4125
pISSN - 0930-7516
DOI - 10.1002/(sici)1521-4125(200002)23:2<122::aid-ceat122>3.0.co;2-7
Subject(s) - hydrosilylation , platinum , catalysis , anhydrous , alkene , chemistry , homogeneous , organic chemistry , homogeneous catalysis , polymer chemistry , thermodynamics , physics
Platinum compounds, e.g. the Speier catalyst and the Karstedt solution, are known to be very active catalysts in the hydrosilylation of 1‐alkene. The use of anhydrous platinum compounds, e.g. Pt(cod) 2 , has proved even more suitable for a technical hydrosilylation reaction. However, as hydrosilylation with this platinum colloid catalyst is carried out in a quasi‐homogeneous system, recycling of the catalyst is quite difficult.