Premium
Adsorptive Stripping Analysis of Trace Nickel at Iridium‐Based Ultramicroelectrode Arrays
Author(s) -
Wang Joseph,
Wang Jianyan,
Adeniyi William K.,
Kounaves Samuel P.
Publication year - 2000
Publication title -
electroanalysis
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.574
H-Index - 128
eISSN - 1521-4109
pISSN - 1040-0397
DOI - 10.1002/(sici)1521-4109(20000101)12:1<44::aid-elan44>3.0.co;2-4
Subject(s) - ultramicroelectrode , iridium , stripping (fiber) , microelectrode , nickel , mercury (programming language) , detection limit , adsorption , chemistry , materials science , analytical chemistry (journal) , chromatography , electrode , electrochemistry , catalysis , cyclic voltammetry , metallurgy , computer science , biochemistry , organic chemistry , composite material , programming language
Lithographically fabricated iridium‐based mercury microelectrode arrays are shown to be very suitable for adsorptive stripping measurements of trace nickel in the presence of the dimethylgloxime complexing agent. Variables affecting the response have been assessed and optimized. The sensor optimization has resulted in a favorable and highly stable response, with good linearity and precision (RSD=1.7 %), and a low detection limit (0.5 µg/L with 30 s adsorption). Such adsorptive stripping performance makes the iridium‐based microelectrode array very attractive for on‐site measurements of trace metals that cannot be plated electrolytically.