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Persistent Honeycomb Structures in Porous and Other Two‐Component Solids
Author(s) -
Kiang Y.H.,
Lee S.,
Xu Z.,
Choe W.,
Gardner G. B.
Publication year - 2000
Publication title -
advanced materials
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 10.707
H-Index - 527
eISSN - 1521-4095
pISSN - 0935-9648
DOI - 10.1002/(sici)1521-4095(200005)12:10<767::aid-adma767>3.0.co;2-b
Subject(s) - materials science , honeycomb , crystallization , honeycomb structure , porosity , hexagonal crystal system , crystal structure , phenylacetylene , component (thermodynamics) , crystal engineering , chemical engineering , nanotechnology , crystallography , composite material , organic chemistry , thermodynamics , catalysis , supramolecular chemistry , chemistry , engineering , physics
Predicting three‐dimensional structure based on the individual components of hybrid structures remains one of the greatest challenges of crystal engineering; however, progress is reported here: For 21 different systems the crystallization of phenylacetylene nitriles with silver triflate salts leads to the same basic hexagonal honeycomb structures (see Figure). A rationalization based on interface minimization is proposed.