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Thienyl(phenyl)iodonium Triflates—Structural, and Linear and Nonlinear Optical Behavior of Hypervalent Iodine Derivatives
Author(s) -
Tykwinski R. R.,
Kamada K.,
Bykowski D.,
Ohta K.,
McDonald R.
Publication year - 2000
Publication title -
advanced materials
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 10.707
H-Index - 527
eISSN - 1521-4095
pISSN - 0935-9648
DOI - 10.1002/(sici)1521-4095(200001)12:2<133::aid-adma133>3.0.co;2-d
Subject(s) - hypervalent molecule , materials science , iodine , nonlinear optical , aryl , nonlinear system , nonlinear optics , photochemistry , polymer chemistry , organic chemistry , chemistry , alkyl , physics , quantum mechanics , metallurgy
The investigation of thienyl and bithienyl iodonium salts as potential nonlinear optical materials is reported. Hypervalent iodine derivatives (see Figure) have been synthesized from the corresponding stannanes, and their structural, electronic, and preliminary nonlinear optical properties examined. UV analysis showed that the iodonium center mediates communication between the pendant aryl and heteroaryl functionalities.