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Synthesis, Structures, and Properties of New Organic Conductors Based on Tellurocycle‐Fused TTF Donor Molecules
Author(s) -
Ojima E.,
Fujiwara H.,
Kobayashi H.,
Kobayashi A.
Publication year - 1999
Publication title -
advanced materials
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 10.707
H-Index - 527
eISSN - 1521-4095
pISSN - 0935-9648
DOI - 10.1002/(sici)1521-4095(199912)11:18<1527::aid-adma1527>3.0.co;2-x
Subject(s) - materials science , electrical conductor , molecule , nanotechnology , organic molecules , organic chemistry , composite material , chemistry
In the search for new organic conductors based on tetrathiafulvalene (TTF) an unsymmetrical tellurocycle‐fused TTF molecule is examined. The crystal structures and electrical properties of the charge‐transfer complex and cation radical salts prepared from this donor molecule are also investigated. The Figure shows the donor–acceptor stacking of its complex with 7,7,8,8‐tetracyanoquinodimethane (TCNQ).