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A Composite from Poly( m ‐phenylenevinylene‐ co ‐2,5‐dioctoxy‐ p ‐phenylenevinylene) and Carbon Nanotubes: A Novel Material for Molecular Optoelectronics
Author(s) -
Curran Seamus A.,
Ajayan Pulickel M.,
Blau Werner J.,
Carroll David L.,
Coleman Johnathan N.,
Dalton Alan B.,
Davey Andrew P.,
Drury Anna,
McCarthy Brendan,
Maier Stephanie,
Strevens Adam
Publication year - 1998
Publication title -
advanced materials
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 10.707
H-Index - 527
eISSN - 1521-4095
pISSN - 0935-9648
DOI - 10.1002/(sici)1521-4095(199810)10:14<1091::aid-adma1091>3.0.co;2-l
Subject(s) - materials science , carbon nanotube , composite number , conjugated system , polymer , diode , conductive polymer , nanotechnology , optoelectronics , composite material
A novel material for molecular optoelectronics consisting of a composite of carbon nanotubes and poly( m ‐phenylenevinylene‐ co ‐2,5‐dioctoxy‐ p ‐phenylenevinylene) (PmPV) is reported. Incorporation of the nanotubes is demonstrated to increase the electrical conductivity of the polymer by up to eight orders of magnitude. The nanotubes appear to act as nanometric heat sinks, preventing the build up of large thermal effects, which degrade these conjugated systems. It is also shown that the composite can be used as the emissive layer in an organic light‐emitting diode, which promises future applications in optoelectronics.

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