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Synthesis, Electrochemical Properties, and Molecular Computations of New Tris(thienyl)methyl Cations
Author(s) -
Cherioux Frederic,
Guyard Laurent,
Audebert Pierre
Publication year - 1998
Publication title -
advanced materials
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 10.707
H-Index - 527
eISSN - 1521-4095
pISSN - 0935-9648
DOI - 10.1002/(sici)1521-4095(199809)10:13<1013::aid-adma1013>3.0.co;2-k
Subject(s) - electrochemistry , materials science , tris , crystal violet , methyl violet , crystal (programming language) , computation , nonlinear optical , crystal structure , inorganic chemistry , combinatorial chemistry , crystallography , chemistry , nonlinear system , electrode , physics , adsorption , computer science , medicine , biochemistry , pathology , algorithm , quantum mechanics , programming language
New octupolar bithiophenic methyl cations belonging to the Crystal Violet family are described (see Figure). The synthesis and electrochemical properties of these cations, which should combine the second‐order nonlinear optical properties of Crystal Violet with the electrochemical properties of heterocycles, are reported along with the findings from molecular computations.

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