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The Role of Defects in the Formation of Mesoporous Silica Fibers, Films, and Curved Shapes
Author(s) -
Yang Hong,
Ozin Geoffrey A.,
Kresge Charles T.
Publication year - 1998
Publication title -
advanced materials
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 10.707
H-Index - 527
eISSN - 1521-4095
pISSN - 0935-9648
DOI - 10.1002/(sici)1521-4095(199808)10:11<883::aid-adma883>3.0.co;2-d
Subject(s) - materials science , mesoporous silica , transmission electron microscopy , mesoporous material , scanning electron microscope , birefringence , mesoporous organosilica , hexagonal crystal system , morphology (biology) , nanotechnology , optical microscope , microscopy , composite material , crystallography , optics , catalysis , chemistry , organic chemistry , physics , biology , genetics
The main goal of this research news article is to describe how different kinds of topological defects that exist in a silicate liquid crystal seed can initiate and direct the growth of particular forms of mesoporous silica. This avenue of investigation emerged from the results of scanning electron microscopy (SEM), transmission electron microscopy (TEM), atomic force microscopy (AFM), and polarized optical microscopy (POM) studies of hexagonal mesoporous silica fibers, films, and curved shapes, which delineated the essential relations between synthesis conditions, morphology, bulk and surface mesostructure, and optical birefringence textures. [1–3] While SEMs of faceted mesoporous silica first appeared in 1992, [4] the recognition, understanding, and significance of morphogenesis of mesoporous silica with curved shapes emerged in a series of papers from our laboratory.