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A New Family of Sulfur Dioxide–Containing TTF Derivatives
Author(s) -
Llacay Josep,
Mata Ignasi,
Molins Elies,
Veciana Jaume,
Rovira Concepció
Publication year - 1998
Publication title -
advanced materials
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 10.707
H-Index - 527
eISSN - 1521-4095
pISSN - 0935-9648
DOI - 10.1002/(sici)1521-4095(199803)10:4<330::aid-adma330>3.0.co;2-q
Subject(s) - tetrathiafulvalene , moiety , sulfone , materials science , crystal structure , crystal (programming language) , sulfur , polymer chemistry , organic chemistry , molecule , chemistry , metallurgy , computer science , programming language
One sulfone group substituted into the tetrathiafulvalene (TTF) core is reported to influence the crystal packing of this family of compounds by permitting hydrogen bonds to be established. In addition, the incorporated 3‐sulfolene moiety is shown to open up a new direction in TTF chemistry by allowing Diels–Alder reactions and related cycloadditions. The synthesis of this family of compounds is described along with the results of a crystal structure investigation. It is shown that the introduction of the 3 sulfolene moiety does not affect the properties of the π‐electron system.