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Very Soft Chemistry: Room Temperature Self‐Assembly of (DABCOH) 2 Sn 3 S 7 , a Microporous Layered Tin( IV ) Sulfide
Author(s) -
Jiang Tong,
Lough Alan,
Ozin Geoffre A.
Publication year - 1998
Publication title -
advanced materials
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 10.707
H-Index - 527
eISSN - 1521-4095
pISSN - 0935-9648
DOI - 10.1002/(sici)1521-4095(199801)10:1<42::aid-adma42>3.0.co;2-w
Subject(s) - microporous material , chalcogenide , soft chemistry , sulfide , materials science , tin , nanotechnology , chemical engineering , protonation , inorganic chemistry , metallurgy , organic chemistry , chemistry , composite material , ion , engineering
Self‐assembled metal chalcogenide open‐framework materials such as that shown in the Figure—a projection on the [100] plane of the structure of a microporous layered tin( IV ) sulfide (DABCOH) 2 Sn 3 S 7 1 , where DABCOH denotes singly protonated 1,8‐diazabicyclooctane—are of interest for chemical sensing applications. A “very soft chemistry”, room temperature synthesis of 1 is reported.