EPR Evidence of the F.C.C.–S.C. Phase Transition in Fullerene C 60  under Hydrostatic Pressure | Zendy

Krupski M. | Zendy; Stankowski J. | Zendy; PiekaraSady L. | Zendy; Kempiński W. | Zendy

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EPR Evidence of the F.C.C.–S.C. Phase Transition in Fullerene C 60 under Hydrostatic Pressure

Author(s) -

Krupski M.,

Stankowski J.,

PiekaraSady L.,

Kempiński W.

Publication year - 1999

Publication title -

physica status solidi (b)

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 0.51

H-Index - 109

eISSN - 1521-3951

pISSN - 0370-1972

DOI - 10.1002/(sici)1521-3951(199903)212:1<47::aid-pssb47>3.0.co;2-u

Subject(s) - fullerene , hydrostatic pressure , crystallite , electron paramagnetic resonance , compressibility , phase transition , materials science , hydrostatic equilibrium , analytical chemistry (journal) , chemistry , crystallography , condensed matter physics , thermodynamics , nuclear magnetic resonance , physics , organic chemistry , quantum mechanics

The EPR study of polycrystalline C 60 shows the evidence of a hydrostatic pressure effect (up to 700 MPa) on the g ‐value of intrinsic defects of polycrystalline C 60 , i.e. C + 60 . The pressure coefficient of the g ‐factor, (∂ g /∂ p ) T , has different values in both f.c.c. and s.c. phases of C 60 . This result is explained by the large compressibility of the fullerene lattice.

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